Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates |
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| Authors: | Kawatsura Motoi Ata Fumio Wada Shohei Hayase Shuichi Uno Hidemitsu Itoh Toshiyuki |
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| Institution: | Department of Materials Science, Faculty of Engineering, Tottori University, Koyama, Tottori, 680-8552, Japan. kawatsur@chem.tottori-u.ac.jp |
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| Abstract: | The regioselectivity in the ruthenium-catalysed allylic alkylation of mono substituted allyl acetates with the malonate anion was highly controlled by Ru3(CO)12 with 2-(diphenylphosphino)benzoic acid, and the linear-type alkylated product was obtained. |
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