Synthesis and Luminescence of Eu‐N2,N6‐Bis(2‐hydroxyethyl)pyridine‐2,6‐dicarboxamide Complexes Containing Mesoporous Material |
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Authors: | Zheng Li Siyu Zuo Jingjian Zhou Xiao Yuan Yishan Song Hua Zhang |
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Institution: | 1. Department of Chemistry, College of Food Science & Technology, Shanghai Ocean University, Shanghai 201306, China;2. State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, Shanghai 200092, China |
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Abstract: | Ligand N2,N6‐bis(2‐hydroxyethyl)pyridine‐2,6‐dicarboxamide (L=BHPC) was synthesized and used to construct lanthanide‐based mesoporous material Eu‐L‐MCM‐41. In the structure of resulting Eu‐L‐MCM‐41, Eu3+ was chelated by BHPC, and the Eu‐L complexes were anchored into the forming MCM‐41 host by the reaction between the hydroxyl group and active Si‐OH. The mesoporous material Eu‐L‐MCM‐41 was characterized by UV, IR, small‐angle X‐ray diffraction (SAXRD) patterns, nitrogen adsorption/desorption isotherms, TGA and fluorescence spectra. The results indicate that ligand and Eu3+ have been introduced into the MCM‐41 host, and Eu‐L‐MCM‐41 exhibits characteristic luminescence of Eu3+. |
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Keywords: | lanthanide mesoporous material luminescence |
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