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Perturbation study via rotational-resolved spectrum in the triplet band d3Δ-a3∏(2, 1) of CO
引用本文:许春燕,杨晓华,郭迎春,吴玲,李伟,陈扬骎.Perturbation study via rotational-resolved spectrum in the triplet band d3Δ-a3∏(2, 1) of CO[J].中国物理 B,2005,14(10):1954-1959.
作者姓名:许春燕  杨晓华  郭迎春  吴玲  李伟  陈扬骎
作者单位:Key Laboratory of Optical and Magnetic Resonance Spectroscopy and Department of Physics,East China Normal University, Shanghai 200062, China;Key Laboratory of Optical and Magnetic Resonance Spectroscopy and Department of Physics,East China Normal University, Shanghai 200062, China;Key Laboratory of Optical and Magnetic Resonance Spectroscopy and Department of Physics,East China Normal University, Shanghai 200062, China;Key Laboratory of Optical and Magnetic Resonance Spectroscopy and Department of Physics,East China Normal University, Shanghai 200062, China;State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics,Chinese Academy of Sciences, Wuhan 430071, China;Key Laboratory of Optical and Magnetic Resonance Spectroscopy and Department of Physics,East China Normal University, Shanghai 200062, China;Key Laboratory of Optical and Magnetic Resonance Spectroscopy and Department of Physics,East China Normal University, Shanghai 200062, China
基金项目:Project supported by the National Natural Science Foundation of China (Grant Nos 10204007 and 10434060) and the Science and Technology Commission of Shanghai Municipality,China (Grant No 04DE14009).
摘    要:The triplet band d3Δ-a3∏ (2, 1) of the CO molecule in the near infrared region of 12350--12850cm-1 has been observed and analysed by taking into account the perturbation interaction between the d3Δ(v = 2) and a3∏ (v = 9) states. The most perturbed lines and most precise perturbation parameters, \alpha2 and \beta2, and electronic perturbation constants,\xi _\e and \eta _\e , for the d3Δ (v= 2) and 3∏ (v = 9) states have been obtained.

关 键 词:扰动参数  CO分子  光谱  红外线  交互作用
收稿时间:2/2/2005 12:00:00 AM
修稿时间:6/2/2005 12:00:00 AM

Perturbation study via rotational-resolved spectrum in the triplet band d3Δ-a3∏(2, 1) of CO
Xu Chun-Yan,Yang Xiao-Hu,Guo Ying-Chun,Wu Ling,Li Wei and Chen Yang-Qin.Perturbation study via rotational-resolved spectrum in the triplet band d3Δ-a3∏(2, 1) of CO[J].Chinese Physics B,2005,14(10):1954-1959.
Authors:Xu Chun-Yan  Yang Xiao-Hu  Guo Ying-Chun  Wu Ling  Li Wei and Chen Yang-Qin
Institution:Key Laboratory of Optical and Magnetic Resonance Spectroscopy and Department of Physics,East China Normal University, Shanghai 200062, China; Key Laboratory of Optical and Magnetic Resonance Spectroscopy and Department of Physics,East China Normal University, Shanghai 200062, China;State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics,Chinese Academy of Sciences, Wuhan 430071, China
Abstract:The triplet band d3Δ-a3∏ (2, 1) of the CO molecule in the near infrared region of 12350--12850cm-1 has been observed and analysed by taking into account the perturbation interaction between the d3Δ(v = 2) and a3∏ (v = 9) states. The most perturbed lines and most precise perturbation parameters, \alpha2 and \beta2, and electronic perturbation constants,\xi _\e and \eta _\e , for the d3Δ (v= 2) and 3∏ (v = 9) states have been obtained.
Keywords:CO molecule  triplet band  perturbation
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