| THE CRYSTAL STRUCTURE OF A NOVEL INCLUSION COMPOUND——TETRAKIS |
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| 引用本文： | 邵美成,李根培,唐有祺,吕品喆,樊玉国,郭东耀.THE CRYSTAL STRUCTURE OF A NOVEL INCLUSION COMPOUND——TETRAKIS[J].中国科学B辑(英文版),1982(6). |
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| 作者姓名： | 邵美成 李根培 唐有祺 吕品喆 樊玉国 郭东耀 |
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| 作者单位： | Institute of Physical Chemistry，Peking University，Institute of Physical Chemistry，Peking University，Institute of Physical Chemistry，Peking University，Institute of Theoretical Chemistry，Jilin University，Institute of Theoretical Chemistry，Jilin University，Institute of Theoretical Chemistry，Jilin University |
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| 摘 要： | The title compound crystallizes in the space group C_5~4 with unit cell constants a=17.900 (5)A, b=18.466 (7)A, c=15.483 (4)A, β=92.78 (2)°and contains four formulaunits of MoFeS_(10)Cl_4N_4C_(34)H_(54). Intensities of 3499 independent reflections are collected withdiffractometer using MoKa radiation. The y coordinates of the Mo atoms are derived fromthe Patterson function. The parameters of the other atoms are found from successive Fourierand difference syntheses. The block-diagonal least-squares refinement for all atoms gives a final discrepancy factorR = 0.054. The result of structure analysis shows that this inclusion compound consists of threekinds of structural units and the oppositely charged complex ions Mo(S_2CN(Et)_2)_4]~ andFeCl_4]~- form a very interesting ionic host framework with infinite tunnels extending alongC direction and containing guest disulfide molecules PhCH_2SSCH_2Ph.
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