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Cyclizations in the reactions of isocyanates with compounds containing active methylene groups in the presence of triethylamine
Authors:O. A. Linchenko  P. V. Petrovskii  I. Yu. Krasnova  V. N. Kalinin  Z. A. Starikova  Yu. G. Gololobov
Affiliation:(1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation
Abstract:
Novel reactions of isocyanates with compounds containing active methylene groups in the presence of triethylamine are described. The reactions afford derivatives of pyrrolidine-2,3,5-trione and barbituric acid. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 844–849, May, 2006.
Keywords:acyclic and heterocyclic compounds with active methylene groups  isocyanates  triethylammonium salts of CH acids  amides of carboxylic acids  thiophosphinicamides
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