Castor oil modified by epoxidation,transesterification, and acrylation processes: Spectroscopic characteristics |
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Authors: | G S Sudha Hemjyoti Kalita Smita Mohanty Sanjay Kumar Nayak |
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Institution: | 1. Department of Plastics Technology, Central Institute of Plastics Engineering and Technology (CIPET), Chennai, Indiasudhasuma@gmail.com;3. Laboratory for Advanced Research in Polymeric Materials (LARPM), Central Institute of Plastics Engineering and Technology (CIPET), Bhubaneswar, India;4. Department of Plastics Technology, Central Institute of Plastics Engineering and Technology (CIPET), Chennai, India;5. Laboratory for Advanced Research in Polymeric Materials (LARPM), Central Institute of Plastics Engineering and Technology (CIPET), Bhubaneswar, India |
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Abstract: | In the present study, castor oil (CO) was modified by epoxidation, transesterification, and acrylation processes. In situ epoxidation method was used to prepare epoxidized castor oil (ECO) in acetic acid with hydrogen peroxide in the presence of Seralite SRC-120 catalyst. Transesterified epoxidized castor oil was synthesized from the reaction of methanol in the presence of sodium methoxide catalyst. The acrylated epoxidized castor oil was synthesized from the reaction of ECO with acrylic acid containing hydroquinone. Chemical structures of modified CO were analyzed by Fourier transform infrared spectroscopy and proton nuclear magnetic resonance spectra analysis. |
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Keywords: | Acrylation castor oil epoxidation FTIR transesterification |
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