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Study on cyanobiphenyl nematic doped by silver nanoparticles
Authors:Karen Kolya Vardanyan  Alexander Daykin  Braxton Kilmer
Affiliation:1. Department of Physics, Southern Illinois University-Edwardsville, Edwardsville, IL, USAkvardan@siue.edu;3. Department of Physics, Southern Illinois University-Edwardsville, Edwardsville, IL, USA
Abstract:We study the effects of doped (1%wt and 2%wt) silver nanoparticles on material properties of nematic liquid crystal: 4-pentyl-4′-cyanobiphenyl. Using differential scanning calorimetry, electrical and dielectric measurements methods, we show that the doped NPs do not affect the nematic’s phase clearing point, lower the dielectric anisotropy, viscosity, switching-off time, and increase the threshold voltage and elasticity of the nematic. We report that the doped materials temperature behaviour of Frederick’s transition threshold voltage and switching-off time, deviates from the expected behaviour for pristine nematics. To explain this anomalous behaviour, we perform data analysis of the governing Frederick’s transition material parameters of studied samples. We show that the elastic parameter of doped samples is not following the predictions of Maier–Saupe theory, which is valid for conventional nematics. We report that the doped samples temperature behaviour of the elastic parameter follows the predictions of the Gelbart and Ben-Shaul theory.
Keywords:Liquid crystal nanocomposites  liquid crystal material properties  electro-optics of nematics  Maier–Saupe theory  Gelbart–Ben-Shaul theory
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