Thermodynamics of stiff macromolecules in the two-dimensional lattice model |
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Authors: | AM Kosevich AS Kovalev ML Polyakov |
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Institution: | Physico-Technical Institute of Low Temperatures, UkrSSR Academy of Sciences, Kharkov, USSR |
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Abstract: | The statistical-thermodynamic analysis of the compact structure (globule) of a flexural stiff macromolecule in the two-dimensional square lattice model is proposed. It is shown that the anisotropy of monomer direction distribution increases with increasing rigidity. The temperature dependence of the globule size turns out to be non-monotonic under fixed pressure. |
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