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Chemiluminecsence in the oxidation of Na2C60 by the (NH4)2Ce(NO3)6 complex in THF
Authors:Bulgakov  R. G.  Akhmadieva  R. G.  Musavirova  A. S.  Golikova  M. T.
Affiliation:(1) Institute of Petrochemistry and Catalysis, Bashkortostan Republic Academy of Sciences and Ufa Research Center of the Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075 Ufa, Russian Federation
Abstract:
Chemiluminescence (lambdamax = 790 nm) in the oxidation of fulleride Na2C60 by the (NH4)2Ce(NO3)6 complex in THF was found. The 3C60* triplet of fullerene formed in the transfer of an electron from the intermediate C60 anion to CeIV was suggested to be the chemiluminescence emitter.
Keywords:fullerene  triplet  chemiluminescence  anions
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