PZT四方相区介电常数εr与晶格畸变关系的研究

从Haun的PZT热力学理论出发，给出了PZT四方相区介电常数ε_r与晶格畸变c/a关 系的基本方程，并深入地根据相关实验资料和物理图像的合理推论，建立了关于晶格畸变c/ a与介电常数ε_r相互依赖的基本关系式.然后，根据该基本关系式仔细地研究了PZT四 方相区晶格畸变c/a对介电常数ε_r影响的物理图像.与相关实验资料比较表明，基本 关系式得到的介电常数ε_r随晶格畸变c/a的变化规律,与相关实验结果相比较，两者 吻合得 关键词： 晶格畸变 r')" href="#">介电常数ε_r 四方相 PZT

Study on the relation between the dielectric properties and lattice distortions in PZT ferroelectric tetragonal phase region

From thermodynamic theory of the lead zirconate titanate(PZT) solid solution sy stem, we have got the basic equation between the dielectric constant ε_r a nd lattice distortion c/a in ferroelectric tetragonal phase region, and base d on the relative experimental data and logical deduction to physics image, we h ave established basic relations between ε_r and c/a. And then, from th e basic relations, we have studied in detail the physics image about lattice dis tortion c/a effect on the dielectric constant ε_r in ferroelectric tet ragonal phase region. A comparison with related experimental results indicates t hat the results of the basic relations are in good agreement with the conclusion s of the experiments. Finally, we have discussed the application range of the ba sic relations and the physics reason of relative warp out of application range. We would emphasize that the basic relations are essentially fitted to all perovs kite structure materials.