Supramolecularly assembled water layers stabilized by sebacic anions in complexes of Zn(II) and Co(II) |
| |
| Authors: | HuiDuo Xian JianFeng Liu GuoLiang Zhao |
| |
| Institution: | 1. Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces; Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, 321004, China
2. College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, 321004, China
|
| |
| Abstract: | Two three-dimensional supramolecular water architectures, Zn(phen)3]2·Zn(C10H16O4)·(H2O)3]·(C10H16O4)2·20H2O (1) and Co(phen)3]2·Co(H2O)6]·(C10H16O4)3·30H2O (2) phen = 1,10-Phenanthroline, C10H16O4 = sebacic dianion], have been synthesized and characterized by IR, elemental analysis, thermogravimetric analysis, and single-crystal X-ray diffractions. The two structures both contain extensive hydrogen bonding between water molecules as well as between water molecules and sebacic anions. The water molecules and sebacic acid O atoms assembled 2D supramolecular corrugated sheets with different morphology in the two complexes. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
