| 烷基和酰基钴化合物合成方法研究进展 |
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| 引用本文： | 田淑芳,郭静玉,任铁钢. 烷基和酰基钴化合物合成方法研究进展[J]. 化学研究, 2011, 22(2): 88-98 |
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| 作者姓名： | 田淑芳 郭静玉 任铁钢 |
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| 作者单位： | 1. 河南大学,基础实验教学中心,河南,开封,475004
2. 河南大学,化学化工学院,河南,开封,475004 |
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| 基金项目： | 河南省教育厅自然科学研究计划项目(20098150005) |
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| 摘 要： | 总结了烷基和酰基钴化合物及其膦配体衍生物的合成方法,综述了其合成方法研究进展.指出烷基和酰基钴化合物是多种重要催化反应如氢甲酰化反应、甲醇同系化反应、酰胺羰基化反应的循环中间体;近年来,烷基和酰基钴化合物因可以催化羰基化聚合反应而引起了广泛的关注.
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| 关 键 词： | 烷基钴 酰基钴 合成方法 羰基聚合反应 研究进展 |
Research progress of synthetic methods of alkyl and acyl cobalt compounds |
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| TIAN Shu-fang,GUO Jing-yu,REN Tie-gang. Research progress of synthetic methods of alkyl and acyl cobalt compounds[J]. Chemical Research, 2011, 22(2): 88-98 |
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| Authors: | TIAN Shu-fang GUO Jing-yu REN Tie-gang |
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| Affiliation: | TIAN Shu-fang1,GUO Jing-yu1,REN Tie-gang2(1.Teaching Center of Basic Experiment,Henan University,Kaifeng 475004,Henan,China,2.College of Chemistry and Chemical Engineering,China) |
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| Abstract: | A review is given about the research progress of the synthetic methods for alkyl and acyl cobalt compounds.It is pointed out that alkyl and acyl cobalt compounds are cyclic intermediates of many important catalytic reactions,such as hydroformylation,methanol homologation and amidocarbonylation reactions.Thanks to their ability to catalyze carbonyl polymerization,alkyl and acyl cobalt compounds are inspiring intensified attention recently. |
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| Keywords: | alkyl cobalt acyl cobalt synthetic method carbonyl polymerization research progress |
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