Ozonolysis of Alkenes and Studies of Reactions of Polyfunctional Compounds: LXV. Ozonolysis of Perfluoro-1-octene in Freon-113 |
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| Authors: | V N Odinokov V R Akhmetova M V Bazunova R G Savchenko E A Paramonov L M Khalilov |
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| Institution: | (1) Academy of Sciences of Bashkortostan Republic and Ufa Research Center of the Russian Academy of Sciences, Institute of Petroleum Chemistry and Catalysis, pr. Oktyabrya 141, Ufa, 450075 Bashkortostan, Russia |
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| Abstract: | Ozonization of perfluoro-1-octene in Freon-113 yields the corresponding ozonide whose catalytic hydrogenation over Pd/C or hydride reduction leads to formation of perfluoroheptanoic acid; the reduction with lithium aluminum hydride gives 2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-1-heptanol. Ozonization of perfluoro-1-octene in Freon-113 containing excess ( 3 equiv) alcohol affords the corresponding perfluoroheptanoic acid ester. |
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