Mercury trifluoroacetate-catalyzed conversion of Se-alkyl phosphoroselenolates into the corresponding phosphates |
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| Authors: | Lucyna A. Wozniak |
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| Affiliation: | Department of Bioorganic Chemistry, Polish Academy of Sciences, Centre of Molecular and Macromolecular Studies, Lodz, PL 90-363, Sienkiewicza 112, Poland |
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| Abstract: | ![]()
The role of mercuric trifluoroacetate as reactive agent and activator in reactions of various Se-alkyl phosphoroselenoates with O- and N-nucleophiles is examined. The formation of mercury-complexed intermediates of putative mixed anhydride-like structure is indicated. |
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| Keywords: | Mercuric trifluoroacetate Mixed anhydrides Nucleophilic substitution Phosphoroselenoates Phosphorothioates |
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