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Tetraphenylantimony carboxylates in the cascade Pd-catalyzed C-phenylation reaction of methyl acrylate in the presence of peroxide |
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| Authors: | Dmitry V Moiseev Vera A Morugova Andrey S Shavirin Victor A Dodonov |
| Institution: | a Department of Organic Chemistry, Nizhnii Novgorod State University, 23 Gagarin Avenue, 603950 Nizhnii Novgorod, Russia b G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, GSP-445, 49 Tropinin Street, 603950 Nizhnii Novgorod, Russia |
| Abstract: | Tetraphenylantimony(V) carboxylates have been used in the palladium-catalyzed C-phenylation reaction of methyl acrylate in the presence of (PhCO2)2 or t-BuOOH under mild conditions (50 °C). The peroxides promote a cascade participation of the organoantimony compound and result in the transfer of three phenyl groups. Organoantimony intermediates have been isolated from the reaction. |
| Keywords: | Antimony(V) Arylation Palladium-catalyzed Peroxide |
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