Hydroformylation in fluorous solvents |
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| Authors: | Dave J Adams Eric G Hope Peter J Pogorzelec |
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| Institution: | a Department of Chemistry, University of Leicester, University Road Leicester LE1 7RH, UK
b Catalyst Evaluation and Optimisation Service, School of Chemistry, University of St. Andrews, St. Andrews, Fife KY16 9ST, UK |
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| Abstract: | The hydroformylation of long chain alkenes under fluorous biphase conditions and in neat perfluorocarbon solvents is reviewed. Special emphasis is placed upon the authors' evaluation of the steric and electronic influence of perfluoroalkylation on catalyst activity, regioselectivity and retention in the fluorocarbon phase. |
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| Keywords: | Fluorous Hydroformylation Rhodium Phosphine |
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