Mild and efficient silylcyanation of ketones catalyzed by cesium fluoride |
| |
| Authors: | Sung Soo Kim Gurusamy Rajagopal Dae Ho Song |
| |
| Affiliation: | Department of Chemistry, Center for Chemical Dynamics, Inha University, 253, Yonghyun-Dong, Nam-Gu, Incheon 402-751, South Korea |
| |
| Abstract: | ![]()
An efficient method of addition of trimethylsilylcyanide to ketones by employing cesium fluoride as catalyst has been described. A variety of aromatic, aliphatic, cyclic and heterocyclic ketones have been converted into their corresponding trimethylsilyl ethers in excellent yield. |
| |
| Keywords: | Silylcyanation CsF TMSCN Ketone Silylethers Cyanohydrins |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
