Nanostructured catalysts for cathodes of oxygen-hydrogen fuel cells |
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| Authors: | V. A. Grinberg T. L. Kulova N. A. Maiorova Zh. V. Dobrokhotova A. A. Pasynskii A. M. Skundin O. A. Khazova |
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| Affiliation: | (1) Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia;(2) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia |
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| Abstract: | ![]()
Bimetallic catalysts platinum-cobalt, platinum-chromium, and platinum-tungsten, deposited onto highly dispersed carbon black from complex cluster-type compounds of corresponding metals with a 1: 1 atomic ratio of metals are developed. The catalysts are characterized by methods of x-ray diffraction analysis and energy dispersive analysis of x-rays. The procedure involving use of a thin-film rotating disk electrode is employed to probe kinetic parameters of the oxygen reduction reaction on the catalysts developed. The investigated binary catalysts exhibit specific electrochemical characteristics that are not inferior and, in some cases, are superior to the characteristics intrinsic to the commercial platinum catalyst E-TEK, when tested in the composition of a gas-diffusion electrode under conditions that are close to real conditions in which cathodes of oxygen-hydrogen fuel cells operate. |
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| Keywords: | bimetallic nanosized catalysts oxygen reduction gas-diffusion electrodes thin-film rotating disk electrode |
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