Symmetric 3,5-pyrazole and isoxazole heterocycles comprising a bent core unit: synthesis and mesomorphic characterisation |
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| Authors: | S Hariprasad H T Srinivasa |
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| Institution: | 1. Department of Post Graduate Studies in Chemistry, Central College Campus, Bangalore University, Bengaluru, Indiahariprasad@bub.ernet.in;3. Department of Post Graduate Studies in Chemistry, Central College Campus, Bangalore University, Bengaluru, India;4. Raman Research Institute, SCM Group, Bengaluru, India |
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| Abstract: | The synthesis and characterisation of some new liquid crystalline (LC) heteroaromatic compounds containing the five-membered pyrazole/isoxazole rings is reported. Some of the compounds exhibited enantiotropic LC properties. The transition temperatures and LC textures of the mesophases were determined using polarised optical microscopy (POM), differential scanning calorimetry (DSC) and X-ray studies. The five-membered heterocyclic compounds with the pyrazole core exhibit smectic C (SmC) phase, whereas isoxazoles show SmC and nematic (N) phases. |
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| Keywords: | liquid crystals heterocycles isoxazoles pyrazoles smectic phases nematic phase |
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