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| Copper methanesulfonate-acetic acid as a novel catalytic system for tetrahydropyranylation of alcohols and phenols | |
| 引用本文： | Min Wang Zhi Guo Song Hong Gong Heng Jiang. Copper methanesulfonate-acetic acid as a novel catalytic system for tetrahydropyranylation of alcohols and phenols[J]. 中国化学快报, 2007, 18(7): 799-802. DOI: 10.1016/j.cclet.2007.05.001 |
| 作者姓名： | Min Wang Zhi Guo Song Hong Gong Heng Jiang |
| 作者单位： | [1]College of Chemistry and Chemical Engineering, Bohai University, Jinzhou 121000, China [2]Center for Science ＆ Technology Experiment, Bohai University, Jinzhou 121000, China [3]School of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China |
| 摘 要： | A synergistic catalytic effect between copper methanesulfonate and acetic acid in tetrahydropyranylation of alcohols and phenol at room temperature under solvent free condition has been described. Both alcohols (primary, secondary and tertiary) and phenols reacted with 3,4-dihydro-2H-pyran smoothly to afford the corresponding tetrahydropyranyl ethers in good yields. |
| 关 键 词： | 四氢吡喃 增效作用 甲烷磺酸铜 乙酸 催化剂 |
| 修稿时间： | 2006-12-22 |
Copper methanesulfonate-acetic acid as a novel catalytic system for tetrahydropyranylation of alcohols and phenols |
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| Min Wang,Zhi Guo Song,Hong Gong,Heng Jiang. Copper methanesulfonate-acetic acid as a novel catalytic system for tetrahydropyranylation of alcohols and phenols[J]. Chinese Chemical Letters, 2007, 18(7): 799-802. DOI: 10.1016/j.cclet.2007.05.001 | |
| Authors: | Min Wang Zhi Guo Song Hong Gong Heng Jiang |
| Affiliation: | 1. College of Chemistry and Chemical Engineering, Bohai University, Jinzhou 121000, China;2. Center for Science & Technology Experiment, Bohai University, Jinzhou 121000, China;3. School of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China |
| Abstract: | A synergistic catalytic effect between copper methanesulfonate and acetic acid in tetrahydropyranylation of alcohols and phenol at room temperature under solvent free condition has been described. Both alcohols (primary, secondary and tertiary) and phenols reacted with 3,4-dihydro-2H-pyran smoothly to afford the corresponding tetrahydropyranyl ethers in good yields. |
| Keywords: | Tetrahydropyranylation Synergistic effect Copper methanesulfonate Acetic acid |
| 本文献已被 CNKI 维普 万方数据 ScienceDirect 等数据库收录！ | |