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Macrocyclic receptor for pertechnetate and perrhenate anions
Authors:Kolesnikov Grigory V  German Konstantin E  Kirakosyan Gayane  Tananaev Ivan G  Ustynyuk Yuri A  Khrustalev Victor N  Katayev Evgeny A
Institution:Department of Chemistry, M.V. Lomonosov Moscow State University, Leninskie gory 1/3, 119992, Moscow, Russian Federation.
Abstract:The design and synthesis of a neutral macrocyclic host that is capable of perrhenate and pertechnetate recognition is described. The anion affinities and underlying coordination modes were estimated by several experimental and theoretical methods including a new technique--reverse (99)Tc NMR titration.
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