Pd-based nanoporous metals for enzyme-free electrochemical glucose sensors |
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Authors: | Chun-Lei Yang Xu-Hai Zhang Guo Lan Lu-Yang Chen Ming-Wei Chen Yu-Qiao Zeng Jian-Qing Jiang |
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Institution: | a Jiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China;
b Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan |
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Abstract: | Nanoporous metals(NPMs) show potential applications as enzyme-free glucose sensors.There are few reports on nanoporous Pd in this area even though their cost is much lower than other NPMs.In this work,we report the formation of Pd-based NPM with improved catalytic activity towards the oxidation of glucose.By dealloying metallic glasses,Pd-based NPMs with bi-continuous networks were obtained.All the Pd-based NPMs show high electrochemical catalytic activity towards glucose oxidation.In this study,NPM with an open,three-dimensional,ligament-channel nanoporous structure resulted by dealloying metallic Pd_(30)Cu_(40)Ni_(10)P_(20).producing a pore size of 11 nm and a ligament size of 7 nm as the best configuration towards the direct oxidation reaction of glucose. |
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Keywords: | Glucose sensors Pd-based NPM Dealloying Electrochemical |
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