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纳米BaAl2S4:Eu2+发光材料的制备及性能
引用本文:申连春,于连香,朱万春,田玉美. 纳米BaAl2S4:Eu2+发光材料的制备及性能[J]. 高等学校化学学报, 2007, 28(10): 1978-1980
作者姓名:申连春  于连香  朱万春  田玉美
作者单位:吉林大学化学学院,长春,130012
摘    要:
采用溶胶-凝胶法合成了纳米荧光粉BaAl2S4:Eu2+, 并对其性能进行了研究.

关 键 词:BaAl2S4Eu2+  光致发光  电致发光  纳米粒子
文章编号:0251-0790(2007)10-1978-03
收稿时间:2006-12-22
修稿时间:2006-12-22

Preparation and Luminescence Characterizations of BaAl2S4: Eu2+ Nanoparticles
SHEN Lian-Chun,YU Lian-Xiang,ZHU Wan-Chun,TIAN Yu-Mei. Preparation and Luminescence Characterizations of BaAl2S4: Eu2+ Nanoparticles[J]. Chemical Research In Chinese Universities, 2007, 28(10): 1978-1980
Authors:SHEN Lian-Chun  YU Lian-Xiang  ZHU Wan-Chun  TIAN Yu-Mei
Affiliation:College of Chemistry, Jilin University, Changchun 130012, China
Abstract:
BaAl2S4:Eu2+ nanoparticles with a size distribution of 50—150 nm were prepared by the sol-gel method. The particles were near spherical and had an intensive green emission when they were excited at 254 nm, after calcining at 1000 ℃ in a mixture of H2S(volume fraction 10%)+N2(volume fraction 90%) for 1.5 h. X-ray diffraction patterns indicate that BaAl2S4:Eu2+ has a cubic structure. The emission and excitation spectra show that emission was from the 4f65d→4f7 transition of the activated Eu2+. The highest photoluminescence(PL) luminance is 420 cd/m2. This study indicate that the BaAl2S4:Eu2+ could be used as photoluminescent nanocomposite materials.
Keywords:2S4Eu2+')"   href="  #"  >BaAl2S4Eu2+  Photoluminescence  Electroluminescence  Nanoparticle
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