| C-甲基取代的1-二茂铁酰氧基杂氮硅三环化合物的合成、表征及FcCOOSi(OCHCH3CH2)(OCH2CH2)2N的晶体结构 |
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| 引用本文： | 常卫星,叶志海,陈莉,彭斌,谢庆兰,孙丽娟.C-甲基取代的1-二茂铁酰氧基杂氮硅三环化合物的合成、表征及FcCOOSi(OCHCH3CH2)(OCH2CH2)2N的晶体结构[J].高等学校化学学报,2007,28(10):1911-1913. |
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| 作者姓名： | 常卫星 叶志海 陈莉 彭斌 谢庆兰 孙丽娟 |
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| 作者单位： | 南开大学元素有机化学国家重点实验室,天津,300071 |
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| 摘 要： | 报道11个新的C-甲基取代的1-二茂铁酰氧基杂氮硅三环化合物.
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| 关 键 词： | 甲基取代 二茂铁 杂氮硅三环 晶体结构 |
| 文章编号： | 0251-0790（2007）10-1911-03 |
| 收稿时间： | 2006-12-07 |
| 修稿时间： | 2006-12-07 |
Synthesis and Characterization of C-Methylsubstituted 1-Ferroceneacyloxysilatranes and Crystal Structure of FcCOOSi(OCHCH3CH2)(OCH2CH2)2N |
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| CHANG Wei-Xing,YE Zhi-Hai,CHEN Li,PENG Bin,XIE Qing-Lan,SUN Li-Juan.Synthesis and Characterization of C-Methylsubstituted 1-Ferroceneacyloxysilatranes and Crystal Structure of FcCOOSi(OCHCH3CH2)(OCH2CH2)2N[J].Chemical Research In Chinese Universities,2007,28(10):1911-1913. |
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| Authors: | CHANG Wei-Xing YE Zhi-Hai CHEN Li PENG Bin XIE Qing-Lan SUN Li-Juan |
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| Institution: | State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China |
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| Abstract: | As silatranes and its related compounds have specific structures and have been demonstrated to show a significent biological activity, eleven new C-methylsubstituted 1-ferroceneacyloxysilatranes were synthesized via the reaction of ferrocenecarboxylic acids and C-methysubstituted 1-ethoxysilatrans. They were characterized by means of IR, 1H NMR and elemental analysis. X-ray structure determination of compound 1 indicates the presence of N→Si bond with a bond length of 0.2113(4) nm. It belongs to monoclinic system, space group P2(1)/c with a=1.4050(16) nm, b=1.2758(14) nm, c=1.1196(12) nm, α=90°, β=108.598(18)°, γ=90°, Z=4. |
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| Keywords: | C-Methylsubstitution Ferrocene Silatrane Crystal structure |
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