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Neue Synthesen von Me2SbX (X = Cl,I) und Kristallstrukturen von Me2SbI und [(Me3Si)2CH]2SbCl
Authors:H J Breunig  H Althaus  R Rsler  E Lork
Abstract:Novel Syntheses of Me2SbX (X = Cl, I) and Crystal Structures of Me2SbI and (Me3Si)2CH]2SbCl The crystal structures of Me2SbI (Me = CH3) and (Me3Si)2CH]2SbCl have been determined by X‐ray methods. Both molecules are pyramidal. The Me2SbI molecules are associated to chains through short intermolecular Sb…I distances (366,7(1) pm) with linear I–Sb…I units (171,87(4)°) and bent Sb–I…Sb bridges (116,83(3)°).
Keywords:Antimony  Crystal structure
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