Neue Synthesen von Me2SbX (X = Cl,I) und Kristallstrukturen von Me2SbI und [(Me3Si)2CH]2SbCl |
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Authors: | H J Breunig H Althaus R Rsler E Lork |
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Abstract: | Novel Syntheses of Me2SbX (X = Cl, I) and Crystal Structures of Me2SbI and (Me3Si)2CH]2SbCl The crystal structures of Me2SbI (Me = CH3) and (Me3Si)2CH]2SbCl have been determined by X‐ray methods. Both molecules are pyramidal. The Me2SbI molecules are associated to chains through short intermolecular Sb…I distances (366,7(1) pm) with linear I–Sb…I units (171,87(4)°) and bent Sb–I…Sb bridges (116,83(3)°). |
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Keywords: | Antimony Crystal structure |
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