| Abstract: | Au(Et2dtc)2]TcNCl4] – Synthesis and Structure Au(Et2dtc)2]TcNCl4] (Et2dtc– = N,N‐diethyldithiocarbamate) is formed by the reaction of Au(CO)Cl] with TcN(Et2dtc)2] in dichloromethane. The solid state structure of the compound is characterized by a large triclinic unit cell (space group, P1, a = 9.422(2), b = 22.594(5), c = 32.153(7) Å, α = 72.64(1), β = 85.19(1), γ = 86.15(1)°, Z = 12) and shows an unusual arrangement due to long‐range contacts between the technetium atoms and sulfur atoms of the Au(Et2dtc)2]+ units (3.45–3.56 Å) which assemble two anions and one cation to {TcNCl4]Au(Et2dtc)2] · TcNCl4]}– moieties. |
