| 一个简捷、高效合成松叶蜂性信息素的方法 |
| |
| 引用本文： | 王子坤,田伟生,潘鑫复.一个简捷、高效合成松叶蜂性信息素的方法[J].有机化学,2007,27(7):866-869. |
| |
| 作者姓名： | 王子坤 田伟生 潘鑫复 |
| |
| 作者单位： | 1. 兰州大学化学化工学院,功能有机分子化学国家重点实验室,兰州,730000
2. 中国科学院上海有机化学研究所,上海,200032 |
| |
| 摘 要： | 以从甾体皂甙元降解的废弃物获取的(4R)-甲基-5-溴戊酸甲酯(4)为起始原料, 通过4与正庚基溴化镁选择性的偶联反应, 经关键合成中间体(4S)-甲基溴代十二烷(7)分别以52%和49%的总收率合成了松叶蜂性信息素(2S,3S,7S)-3,7-二甲基十五-2-醇乙酸酯(2)和丙酸酯(3).
|
| 关 键 词： | 松叶蜂性信息素 (4R)-甲基-5-溴戊酸甲酯 偶联反应 |
| 收稿时间： | 2007-1-12 |
| 修稿时间： | 2007-01-112007-04-05 |
A Concise Synthesis of the Sex Pheromones of Pine Sawflies |
| |
| WANG Zi-Kun,TIAN Wei-Sheng,PAN Xin-Fu.A Concise Synthesis of the Sex Pheromones of Pine Sawflies[J].Chinese Journal of Organic Chemistry,2007,27(7):866-869. |
| |
| Authors: | WANG Zi-Kun TIAN Wei-Sheng PAN Xin-Fu |
| |
| Institution: | a State Key Laboratory of Applied Organic Chemistry, Department of Chemistry, Lanzhou University, Lanzhou 730000; b Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032 |
| |
| Abstract: | Starting from methyl (R)-5-bromo-4-methylpentanoate (4) obtained from the waste in the degra-dation of steroid sapogenin, (2S,3S,7S)-3,7-dimethylpentadecan-2-yl acetate (2) and propionate (3) were synthesized via the coupling reaction of 4 with heptyl Grignard in 52% and 49% overall yields respectively. |
| |
| Keywords: | sex pheromone of Pine sawfly methyl (R)-5-bromo-4-methylpentanoate coupling reaction |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《有机化学》浏览原始摘要信息 |
| 点击此处可从《有机化学》下载免费的PDF全文 |
|
