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Synthesis of the C1-C16 fragment of the ajudazols |
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| Authors: | Ben A EganMichael Paradowski Lynne H ThomasRodolfo Marquez |
| Institution: | a WestChem, School of Chemistry, University of Glasgow, Glasgow G12 8QQ, UK b Pfizer Global R&D, Sandwich, Kent, CT13 9NJ, UK c Department of Chemistry, University of Bath, BA2 7AY, UK |
| Abstract: | The synthesis of the C1-C16 framework of the ajudazols has been achieved taking advantage of a highly selective isobenzofuran oxidative rearrangement and a key Stille coupling to introduce the key C14-C15 bond. |
| Keywords: | Ajudazol Isobenzofuran Oxidative rearrangement |
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