Electrooxidation of 2,3-dihydro-1H-1,3,2-diazaphospholes |
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| Authors: | V V Yanilkin V I Morozov F F Nigmadzyanov T V Gryaznova A M Kibardin |
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| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088 Kazan', Russian Federation |
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| Abstract: | Electrooxidation of 2-R-1,3-dibutyl-4,5-dimethyl-2,3-dihydro-1H-1,3,2-diazaphospholes with tri- and tetracoordinated phosphorus atoms were studied. Reversible one-electron oxidation gives
radical cations at potentials of −0.37 to +0.36 V. Magnetic parameters of the radical cations were measured.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1522–1524, August, 1998. |
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| Keywords: | electrooxidation ESR heterocycles dihydrodiazaphospholes |
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