| 低热固相合成类金刚石型配位聚合物Zn(INA)2 |
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| 引用本文： | 张若冰,陈金喜,孟伟伟,王 艳,雷立旭.低热固相合成类金刚石型配位聚合物Zn(INA)2[J].无机化学学报,2009,25(9):1668-1671. |
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| 作者姓名： | 张若冰 陈金喜 孟伟伟 王 艳 雷立旭 |
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| 作者单位： | 东南大学化学化工学院,南京,211189 |
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| 基金项目： | 东南大学引进人才科研启动基金 |
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| 摘 要： | 用低热固相合成法制备了配位聚合物Zn(INA)2(HINA=异烟酸),并用X射线粉末衍射,SEM等方法对产物进行了表征.该合成方法在近室温下进行,不需溶剂的参与,反应迅速,且产率接近100%,是一种高效简便的绿色合成方法.制得的配位聚合物Zn(INA)2具有四面体结构的四配位Zn2+中心,形成了类似金刚石结构的三维框架,并具有较好的热稳定性.
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| 关 键 词： | 低热固相合成 X射线粉末衍射 异烟酸 |
Synthesis of a Diamond-Like Coordination Polymer, Zn(INA)2 by Solid State Reaction at Lower Heating Temperature |
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| ZHANG Ruo-Bing,CHEN Jin-Xi,MENG Wei-Wei,WANG Yan and LEI Li-Xu.Synthesis of a Diamond-Like Coordination Polymer, Zn(INA)2 by Solid State Reaction at Lower Heating Temperature[J].Chinese Journal of Inorganic Chemistry,2009,25(9):1668-1671. |
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| Authors: | ZHANG Ruo-Bing CHEN Jin-Xi MENG Wei-Wei WANG Yan and LEI Li-Xu |
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| Institution: | School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189,School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189,School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189,School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189 and School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189 |
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| Abstract: | |
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| Keywords: | solid state synthesis at lower heating temperature X-ray powder diffraction isonicotinic acid |
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