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Evaluation of environmental filtration control of engineered nanoparticles using the Harvard Versatile Engineered Nanomaterial Generation System (VENGES)
Authors:Candace S.-J. Tsai   Manuel E. Echevarría-Vega   Georgios A. Sotiriou   Christopher Santeufemio   Daniel Schmidt   Philip Demokritou  Michael Ellenbecker
Affiliation:(1) NSF Center for High-rate Nanomanufacturing (CHN), University of Massachusetts Lowell, One University Avenue, Lowell, MA 01854, USA;(2) Industrial Engineering Department, University of Puerto Rico Mayag?ez, Mayag?ez, PR 00681, USA;(3) Particle Technology Laboratory, Department of Mechanical and Process Engineering, Swiss Federal Institute of Technology (ETH Zurich), 8092 Zurich, Switzerland;(4) Campus Materials Characterization Laboratory, University of Massachusetts Lowell, One University Avenue, Lowell, MA 01854, USA;(5) Department of Plastic Engineering, University of Massachusetts Lowell, One University Avenue, Lowell, MA 01854, USA;(6) Center for Nanotechnology and Nanotoxicology at the Harvard School of Public Health, Boston, MA 02115, USA
Abstract:Applying engineering controls to airborne engineered nanoparticles (ENPs) is critical to prevent environmental releases and worker exposure. This study evaluated the effectiveness of two air sampling and six air cleaning fabric filters at collecting ENPs using industrially relevant flame-made engineered nanoparticles generated using a versatile engineered nanomaterial generation system (VENGES), recently designed and constructed at Harvard University. VENGES has the ability to generate metal and metal oxide exposure atmospheres while controlling important particle properties such as primary particle size, aerosol size distribution, and agglomeration state. For this study, amorphous SiO2 ENPs with a 15.4 nm primary particle size were generated and diluted with HEPA-filtered air. The aerosol was passed through the filter samples at two different filtration face velocities (2.3 and 3.5 m/min). Particle concentrations as a function of particle size were measured upstream and downstream of the filters using a specially designed filter test system to evaluate filtration efficiency. Real time instruments (FMPS and APS) were used to measure particle concentration for diameters from 5 to 20,000 nm. Membrane-coated fabric filters were found to have enhanced nanoparticle collection efficiency by 20–46 % points compared to non-coated fabric and could provide collection efficiency above 95 %.
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