The first indium-organic two-dimensional layer network with rhombus grids |
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| Authors: | Zheng-Zhong Lin Rui-hu Wang Lei Han Rong Cao |
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| Institution: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China |
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| Abstract: | The indium(III)-organic compound In(HBtc)2(4,4′-bpy)](4,4′-Hbpy)(H2O)0.5 (Btc=1,3,5-benzenetricarboxylate, 4,4′-bpy=4,4′-bipyridine) has been synthesized under hydrothermal condition and characterized by IR, fluorescent spectroscopy, TGA and single-crystal X-ray diffraction analyses. The compound crystallizes in monoclinic, space group P2(1)/c, a=17.0884(2) Å, b=12.28390(10) Å, c=17.9456(4) Å, β=104.1920(10)°, V=3652.03(10) Å3, Z=4, R1=0.0572 and wR2=0.1116 I>2σ(I)]. All the indium atoms in the compound are hepta-coordinated and link 1,3,5-benzenetricarboxylate forming a 2-D layer structure with rhombus grids. |
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| Keywords: | Hydrothermal synthesis Crystal structure Indium (III) 1 3 5-benzenetricarboxylate 4 4&prime -bipyridine |
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