A novel three-dimensional inorganic framework: hydrothermal synthesis and crystal structure of CuMo3O10·H2O |
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| Authors: | Chungui Tian Yangguang Li Lin Xu Changwen Hu Jun Peng |
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| Affiliation: | Department of Chemistry, Institute of Polyoxometalate Chemistry, Northeast Normal University, Changchun 130024, PR China |
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| Abstract: | A novel three-dimensional inorganic bimetallic compound Cu[Mo3O10]·H2O 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Compound 1 crystallizes in the orthorhombic system, space group Pnma, a=8.6085(17) Å, b=7.5822(15) Å, c=13.690(3) Å, V=893.6(3) Å3, Z=4, λ(MoKα) = 0.71073 Å (R(F)=0.0357 for 1101 reflections). The structure of compound 1 is based on [{Mo3O10}2−]∞ isopolyoxomolybdate chains bonded together with CuO4 tetrahedra into a three-dimensional inorganic open framework. Three types of Mo-Cu layers and one-dimensional tunnels are observed in the title compound. |
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| Keywords: | Crystal structure Bimetallic open framework Isopolyoxomolybdate chains Hydrothermal synthesis |
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