An ionothermal synthetic approach to porous polyoxometalate-based metal-organic frameworks |
| |
| Authors: | Hai Fu Chao Qin Ying Lu Zhi-Ming Zhang Yang-Guang Li Zhong-Min Su Wen-Liang Li En-Bo Wang |
| |
| Affiliation: | Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (China). |
| |
| Abstract: | ![]()
Pretty porous POMs: Ionothermal synthesis was applied to prepare porous POM-based open frameworks. The structural integrity remains unchanged until 300?°C; most importantly, the bulky tetrabutylammonium cations within their nanosized channels can be replaced by transition-metal ions through a cation-exchange process, and subsequent gas adsorption measurements confirm their permanent porosity. |
| |
| Keywords: | adsorption copper ionic liquids polyoxometalates porous materials |
| 本文献已被 PubMed 等数据库收录！ |
