Peroxidase catalyzed polymerization of phenol |
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Authors: | Palligarnai T Vasudevan Luting Olivia Li |
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Institution: | (1) Department of Chemical Engineering, Kingsbury Hall, University of New Hampshire, 03824 Durham, NH |
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Abstract: | effect of horseradish peroxidase (HRP) and H2O2 concentrations on the removal efficiency of phenol, defined as the percentage of phenol removed from solution as a function
of time, has been investigated. When phenol and H2O2 react with an approximately one-to-one stoichiometry, the phenol is almost completely precipitated within 10 min. The reaction
is inhibited at higher concentrations of H2O2. The removal efficiency increases with an increase in the concentration of HRP, but an increase in the time of treatment
cannot be used to offset the reduction in removal efficiency at low concentrations of the enzyme, because of inactivation
of the enzyme. One molecule of HRP is needed to remove approximately 1100 molecules of phenol when the reaction is conducted
at pH 8.0 and at ambient temperature. |
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Keywords: | Horseradish peroxidase phenol hydrogen peroxide |
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