New possible mode of ligand-metal cooperation in PC(sp3)P pincer complexes |
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| Authors: | Musa Sanaa Romm Ronit Azerraf Clarite Kozuch Sebastian Gelman Dmitri |
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| Institution: | Institute of Chemistry, The Hebrew University, Edmond Safra Campus, 91904, Jerusalem, Israel. |
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| Abstract: | Ligand-metal cooperation in iridium and platinum complexes bearing tricyclic dibenzobarrelene-based PC(sp(3))P pincer ligands is discussed. We demonstrated that the carbon-metal bond in these complexes may be efficiently cleaved and regenerated via 1,2-addition/elimination reactions. |
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