| 5,9,14,18,23,27,32,36-八烷氧基2,3-萘酞菁镍(Ⅱ)的结构与光谱性质关系的研究 |
| |
| 引用本文： | 杨素苓,刘尔生,庄惠生,陈耐生,黄金陵,卜平,吴谊群,左霞,毛桂杰,段武彪.5,9,14,18,23,27,32,36-八烷氧基2,3-萘酞菁镍(Ⅱ)的结构与光谱性质关系的研究[J].结构化学,1997(2). |
| |
| 作者姓名： | 杨素苓 刘尔生 庄惠生 陈耐生 黄金陵 卜平 吴谊群 左霞 毛桂杰 段武彪 |
| |
| 作者单位： | 福州大学化学系!福州，350002，福州大学化学系!福州，350002，福州大学化学系!福州，350002，福州大学化学系!福州，350002，福州大学化学系!福州，350002，黑龙江大学化学系!哈尔滨，150080，黑龙江大学化学系!哈尔滨，150080，黑龙江大学化学系!哈尔滨，150080，黑龙江大学化学系!哈尔滨，150 |
| |
| 基金项目： | 黑龙江省自然科学基金，福建省科委资助 |
| |
| 摘 要： | 测定了一组八烷氧基萘酞菁镍（Ⅱ）配合物Ni（Ⅱ）（RO）8NPC（R＝C4H9，C8H17，C12H25，NPC＝C48H16N8）在5种有机溶剂（Py、DMSO、DMF、CH2Cl2、C6H12）中的电子吸收光谱和荧光光谱，研究了这些配合物的结构与光谱的关系。结果表明该系列RO取代萘酞菁镍（Ⅱ）配合物的Q带吸收光谱比无取代的红移75nm左右，荧光光谱屯相应红移50～80nm，而溶剂对其影响不大。
|
| 关 键 词： | 八烷氧基萘酞菁镍 电子吸收光谱 荧光光谱 |
Study of Relation between Structure and Spectra of Some 5,9,14,18,23,27,32,36-Octaalkoxy naphthalocyanines Nickel (Ⅱ) |
| |
| YANG Su-Ling, LIU Er-Sheng, ZHUANG Hui-Sheng,CHEN Nai-Sheng ,HUANG Jin-Ling.Study of Relation between Structure and Spectra of Some 5,9,14,18,23,27,32,36-Octaalkoxy naphthalocyanines Nickel (Ⅱ)[J].Chinese Journal of Structural Chemistry,1997(2). |
| |
| Authors: | YANG Su-Ling LIU Er-Sheng ZHUANG Hui-Sheng CHEN Nai-Sheng HUANG Jin-Ling |
| |
| Abstract: | Absorption spectra and fluorescence spectra of a series of octaalkoxy naphthalocyanine nickel (Ⅱ) complexes NiNPc and Ni(RO),NPc(R=C4H9 C8H17, C12H25, NPc=C48,H16N8) have been measured in DMSO, DMF, Py, CH2Cl2 and C6H12. The effects of solvents on these spectra and the relations between structure and spectra of these complexes were studied. The results show that the Q-band absorption maximum and the fluorescence emission spectra of Ni(OR)8NPc are shifted 75 nm and 50~80 nm further to red than those of NiNPc respectively. This means that increasing conjugation in NiNPc in addition to RO will lead to the absorption maximum shifting towards longer wavelengths. |
| |
| Keywords: | octaalkoxy naphthalocyanine nickel absorption spetrum fluorescence spectrum |
| 本文献已被 CNKI 等数据库收录！ |
|
