| 基于K2S2O8-KOH体系合成羟基葫芦[6]脲的研究 |
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| 引用本文： | 王阳,王巧纯.基于K2S2O8-KOH体系合成羟基葫芦[6]脲的研究[J].化学通报,2018,81(4):376-379. |
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| 作者姓名： | 王阳 王巧纯 |
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| 作者单位： | 华东理工大学 精细化工研究所 结构可控先进功能材料及其制备教育部重点实验室,华东理工大学 精细化工研究所 结构可控先进功能材料及其制备教育部重点实验室 |
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| 基金项目： | 国家自然科学基金项目（21572063；21372076） |
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| 摘 要： | 基于已报道的以葫芦脲-过硫酸钾体系的羟基葫芦脲合成反应,本文研究了加入KOH对原体系的影响,在优化的反应条件下,可以较理想的产率(27%)得到目标产物。产物的结构经~1H NMR、~(13)C NMR和HR-ESI-MS进行确证。
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| 关 键 词： | 羟基葫芦[6]脲 过硫酸钾 氢氧化钾 合成 |
| 收稿时间： | 2017/11/21 0:00:00 |
| 修稿时间： | 2017/12/26 0:00:00 |
Investigation of synthesis of Perhydroxycucurbi[6]turil Based on the System Involving K2S2O8-KOH |
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| Wang-Yang and Wang Qiao-Chun.Investigation of synthesis of Perhydroxycucurbi[6]turil Based on the System Involving K2S2O8-KOH[J].Chemistry,2018,81(4):376-379. |
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| Authors: | Wang-Yang and Wang Qiao-Chun |
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| Institution: | Key Laboratory for Advanced Materials and Institute of Fine Chemicals,School of Chemistry Molecular Engineering,East China University of Science Technology,Shanghai,Key Laboratory for Advanced Materials and Institute of Fine Chemicals,School of Chemistry Molecular Engineering,East China University of Science Technology,Shanghai |
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| Abstract: | Based on the reported method using cucurbiturils-potassium peroxydisulfate, the effect of the extra addition of KOH on the synthesis of perhydroxycucurbi6]turils was investigated,the desired product and adequate yield of 27 % was obtained. The product was further identified by the 1 H NMR, 13 C NMR and HR-ESI-MS. |
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| Keywords: | perhydroxycucurbi[6]turils KPS KOH synthesis |
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