Modular construction and hierarchical gelation of organooxotin nanoclusters derived from simple building blocks |
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| Authors: | Hahn Uwe Hirst Andrew R Delgado Juan Luis Kaeser Adrien Delavaux-Nicot Béatrice Nierengarten Jean-Francois Smith David K |
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| Institution: | Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse 4, France. |
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| Abstract: | Mixtures of an appropriate carboxylic acid and n-butylstannoic acid constitute modular gelation systems, in which the formation of a well-defined 'tin-drum' nanocluster subsequently underpins the hierarchical assembly of nanostructured fibres, which form self-supporting gel-phase networks in organic solvents. |
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