The Haloform Reaction in the Presence of Cyclodextrins |
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| Authors: | Francesco Trotta Davide Cantamessa Marco Zanetti |
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| Affiliation: | (1) Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali dell'Universitá di Torino, Via Pietro Giuria 7, 10125 Torino, Italy |
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| Abstract: | Cyclodextrins act as inverse phase transfer catalystsin the oxidation of methyl ketones by hypochloride(the haloform reaction). The reaction is affected by thechoice and the amount of cyclodextrin. The reactionproceeds under mild reaction conditions and itprovides only the corresponding carboxylic acid asreaction product. No organic solvent is required. |
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| Keywords: | cyclodextrins inverse phase transfer catalysis haloform reaction |
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