| Synthesis,Crystal Structure,and Magnetic and Water-induced Reversible Transformation Properties of {[Ni（IBG）（g-HeO）（HeO）e].2HeO}n |
| |
| 作者姓名： | XU Han LIU Bin PAN Zhao-Rui |
| |
| 作者单位： | [1]Department of Chemistry and Chemical Engineering, Huangshan University, Huangshan 245041, China [2]Key Laboratory of Synthetic andNatural Functional Molecule Chemistry,College of Chemistry ＆ Material, Northwest University, Xi ＇an 710069, China [3]Biochemical and Environmental Engineering College, Nanjing Xiaozhuang University, Nanjing 211171, China |
| |
| 基金项目： | This work was supported by the Universities Natural Science Research Project of Anhui Province （Nos. KJ2013B274 and 2011SQRLI41） and Natural Science Foundation for the Youth （No. 21101126） |
| |
| 摘 要： | A novel NiII complex {Ni（IBG）μ-H20）（H2O）2]·2H2O}n 1 （H2IBG = isophthaloyl- bisglycine） has been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectra, and thermogravimetric analysis. It crystallizes in monoclinic, space group P2/c with a = 15.40（2）, b = 6.960（10）, c = 7.865（11） A, β = 90.32（3）°, F = 843（2） A3, Z = 2, C12H18NiN2Oll, Mr = 424.99, Dc = 1.675 g/cm3, F（000） = 440,/a（MoKa） = 1.214 mm-1, the final R = 0.0514 and wR = 0.1247 for 1078 observed reflections with I 〉 2σ（I）. In the structure, each NiH center is situated in the center of a rather regular octahedron. Moreover, thermal stability has been studied and magnetic measurements show antiferromagnetic interactions for this complex.
|
| 关 键 词： | 晶体结构 可逆转换 合成 单晶X-射线衍射 反铁磁相互作用 属性 磁性 镍 |
| 本文献已被 维普 等数据库收录！ |
|
