Benzene-templated hydrothermal synthesis of metal-organic frameworks with selective sorption properties |
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Authors: | Choi Eun-Young Park Kyungsoo Yang Cheol-Min Kim Hyejin Son Jung-Ho Lee Soon W Lee Young Hee Min Dongwon Kwon Young-Uk |
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Affiliation: | Department of Chemistry and BK-21 School of Molecular Sciences, Sungkyunkwan University, Suwon, 440-746, Korea. |
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Abstract: | In this paper, we report two metal-organic frameworks [Co3(ndc)3(bipyen)(1.5)]H2O (1) and [Co2(ndc)2bipyen)]C6H6.H2O (2) (bipyen=trans-1,2-bis(4-pyridyl)ethylene, H2ndc=2,6-naphthalenedicarboxylic acid). These compounds were both synthesized from identical hydrothermal reaction conditions except that benzene was added to the reaction for 2. Crystal structures show that the two compounds have triply interpenetrated three-dimensional frameworks and these frameworks have the same primary structure of a two-dimensional network of interconnected [Co2(O2CR)(4/2)] (R=naphthalene group) paddle-wheels and bridging bipyen ligands. Both compounds have guest water molecules and, in addition, 2 has guest benzene molecules. Structural transformations of the host accompanied guest removal, which can be monitored by powder X-ray diffraction. N2 adsorption data of 2 show that there are two different types of pores corresponding to the benzene and water pores. Upon exposure to vapors of several organic molecules, the heat-treated sample of 2 adsorbs benzene and cyclohexene, but does not adsorb toluene, (o-, m-, and p-)xylenes, cycloheptatriene, or cyclohexane. |
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Keywords: | adsorption benzene templates host–guest systems hydrothermal synthesis metal–organic frameworks |
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