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SINGLE Mo_(n)Fe_(4-n)S_(4) (n=0, 1, 2) CUBANE-LIKE CLUSTERS: PREPARATION FROM COMBI-NATION OF DINUCLEAR COMPLEXES AND THE STRUCTUREOF [Mo_(2)Fe_(2)S_(4)(C_(4)H_(8)dtc)_(6)]·3.5C_(2)H_(2)Cl_(4)
引用本文:刘秋田,黄梁仁,雷新建,王舫,陈冬玲,卢嘉锡.SINGLE Mo_(n)Fe_(4-n)S_(4) (n=0, 1, 2) CUBANE-LIKE CLUSTERS: PREPARATION FROM COMBI-NATION OF DINUCLEAR COMPLEXES AND THE STRUCTUREOF [Mo_(2)Fe_(2)S_(4)(C_(4)H_(8)dtc)_(6)]·3.5C_(2)H_(2)Cl_(4)[J].中国科学B辑(英文版),1991(9).
作者姓名:刘秋田  黄梁仁  雷新建  王舫  陈冬玲  卢嘉锡
作者单位:Fujian Institute of Research on the Structure of Matter,Academia Sinica and Fuzhou Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Academia Sinica and Fuzhou Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Academia Sinica and Fuzhou Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Academia Sinica and Fuzhou Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Academia Sinica and Fuzhou Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Academia Sinica and Fuzhou Laboratory of Structural Chemistry
基金项目:Project supported by the National Natural Science Foundation of China,the Science Foundation of Chinese Academy of Sciences.
摘    要:Three types of unit combinations, FeS2Fe + FeS2Fe, FeS2Fe + MoS2Fe and MoS2Mo + MoS2Mo, lead to Fe4S4, MoFe3S4 and Mo2Fe2S4 cubane-like clusters, respectively. A new doubly bridged single cubane cluster Mo2Fe2S4(C4H8dtc)6]·3.5C2H2Cl4 has been obtained and its structure is discussed.

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