| 3,6-二(N-咪唑/苯并咪唑基)哒嗪配体配合物的合成、结构、荧光及光催化性能 |
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| 引用本文： | 李金萍,范建中,王多志.3,6-二(N-咪唑/苯并咪唑基)哒嗪配体配合物的合成、结构、荧光及光催化性能[J].无机化学学报,2013,29(18). |
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| 作者姓名： | 李金萍 范建中 王多志 |
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| 作者单位： | 新疆大学化学化工学院, 乌鲁木齐 830046,新疆大学化学化工学院, 乌鲁木齐 830046,新疆大学化学化工学院, 乌鲁木齐 830046 |
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| 基金项目： | 国家自然科学基金(No.21361026)资助项目。 |
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| 摘 要： | 用溶剂热法设计、合成了4个金属-有机配合物Mn(L1)4(OH)2](1),{MnL1(H2O)4]SO4}n(2),CdL2(NO3)2]n(3)和{Co(L2)2](PF6)2}n(4),(L1=3,6-二(N-咪唑基)哒嗪,L2=3,6-二(N-苯并咪唑基)哒嗪),并通过元素分析、红外、X射线单晶衍射对配合物结构进行了表征,测试结果表明配合物1具有单核结构,2为一维链结构,配合物3和4均为二维网状结构。此外,对配合物3和4的固态荧光性能及光催化的性能做了进一步研究。
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| 关 键 词： | 配合物 晶体结构 荧光性能 |
| 收稿时间： | 1/5/2016 12:00:00 AM |
| 修稿时间： | 3/1/2016 12:00:00 AM |
Metal-Organic Complexes Based on 3,6-Bis(N-imidazolyl/benzimidazolyl) Pyridazine:Syntheses, Structures, Emission and Photocatalytic Properties |
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| LI Jin-Ping,FAN Jian-Zhong and WANG Duo-Zhi.Metal-Organic Complexes Based on 3,6-Bis(N-imidazolyl/benzimidazolyl) Pyridazine:Syntheses, Structures, Emission and Photocatalytic Properties[J].Chinese Journal of Inorganic Chemistry,2013,29(18). |
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| Authors: | LI Jin-Ping FAN Jian-Zhong and WANG Duo-Zhi |
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| Institution: | College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China,College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China and College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China |
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| Abstract: | Four new metal-organic coordination polymers namely, Mn(L1)4(OH)2](1), {MnL1(H2O)4](SO4)}n(2), CdL2(NO3)2]n(3), {Co(L2)2](PF6)2}n(4)(L1=3,6-bis(N-imidazolyl) pyridazine, L2=3,6-bis(N-benzimidazolyl) pyridazine] have been synthesized under solvothermal conditions and characterized by elemental analyses, IR spectra as well as single-crystal X-ray diffraction analysis. The analysis reveals that complex 1 has a mononuclear structure, and complex 2 features a 1D structure. Complexes 3 and 4 exhibit a 2D network structure. The fluorescence and photocatalytic activity of the complexes 3 and 4 have been investigated and discussed. CCDC:1444988, 1; 1444989, 2; 1022876, 3; 1022877, 4. |
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| Keywords: | complex crystal structure luminescent property |
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