The bridging bidentate perchlorato group in ReO3(ClO4), ReO3(ClO4Cl2O6 and Sb2Cl6(O)(OH)(ClO4), a vibrational analysis |
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| Authors: | Cunin Frederique Favier Frédéric Pascal Jean Louis |
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| Institution: | Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques, UMR CNRS 5072, Case Courrier 015, Université de Montpellier 2, Sciences et Techniques du Languedoc, 34095 Montpellier Cedex 5, France. fcunin@ucsd.edu |
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| Abstract: | Raman and infrared analysis of the new compounds: ReO3(ClO4), an ivory-white solid, and (ClO2)xReO3(ClO4)1+x (x < or = 1), an orange-red chloryl salt, showed that bridging bidentate ClO4] and terminal ReO3 groups are present in both complexes. Vibrational data on ClO4] in ReO3(ClO4) were compared to those obtained experimentally and by DFT calculation on a bridging bidentate ClO4] in Sb2Cl6(O)(OH)(ClO4). |
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