Selective synthesis of C-arylglycosides via Cp*RuCl-catalyzed partially intramolecular cyclotrimerizations of C-alkynylglycosides |
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| Authors: | Yamamoto Yoshihiko Saigoku Tomoaki Nishiyama Hisao Ohgai Takashige Itoh Kenji |
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| Affiliation: | Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya, 464-8603, Japan. yamamoto@apchem.nagoya-u.ac.jp |
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| Abstract: | ![]()
In the presence of catalytic amounts of Cp*RuCl(cod), the partially intramolecular cyclotrimerizations of various C-alkynylglycosides and C-diynylglycosides proceeded at ambient temperature to afford C-arylglycosides. |
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