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TiN和Ti1-xSixNy薄膜的微观结构分析
引用本文:张晨辉,雒建斌,李文治,陈大融. TiN和Ti1-xSixNy薄膜的微观结构分析[J]. 物理学报, 2004, 53(1): 182-188
作者姓名:张晨辉  雒建斌  李文治  陈大融
作者单位:清华大学摩擦学国家重点实验室,北京 100084
基金项目:国家自然科学基金(批准号:90206022)和杰出青年基金(批准号:50025515)资助的课题.
摘    要:
使用x射线衍射(XRD)、x射线光电子谱(XPS)、高分辨透射电子显微镜(HRTEM)和原子力显微镜(AFM)多种观测手段分析了TiN薄膜和Ti1-xSixNy纳米复合薄膜的微观结构.实验分析证明Ti1-xSixNy薄膜是由直径为3—5nm的纳米晶TiN和非晶Si3N4相构成,并且Ti1-xSix关键词:纳米复合薄膜自由能表面粗糙度TiN1-xSixNy')" href="#">Ti1-xSixNy

关 键 词:纳米复合薄膜  自由能  表面粗糙度  TiN  Ti1-xSixNy
文章编号:1000-3290/2004/53(01)/0182-07
收稿时间:2003-03-14

The study on the microstructure of TiN and Ti1-xSixNy coatings
Zhang Chen-Hui,Luo Jian-Bin,Li Wen-Zhi and Chen Da-Rong. The study on the microstructure of TiN and Ti1-xSixNy coatings[J]. Acta Physica Sinica, 2004, 53(1): 182-188
Authors:Zhang Chen-Hui  Luo Jian-Bin  Li Wen-Zhi  Chen Da-Rong
Abstract:
The microstructure of TiN coatings and Ti1-xSixNy nanocomposite coatings was studied by means of x-ray diffrection, x-ray photoelection spectroscopy, high resolution transmission electron microscopy and atomic force microscopy. The results showed that the Ti1-xSixNy coatings consisted of TiN nanocrystallites with grain size of 3-5nm and amorphous Si3N4 phase. The roughness of Ti1-xSixNy coatings was less than that of TiN coatings prepared under the same conditions. The orientation of TiN crystals in the Ti1-xSixNy coatings was discussed on the basis of interface energy.
Keywords:nanocomposite coating   free energy   roughness   TiN   Ti1-xSixNy
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