Palladium complex of 6-(2-hydroxy-5-methylphenyl)-3-(pyridin-2-yl)-1,2,4-triazin-5(2<Emphasis Type="Italic">H</Emphasis>)-one: Synthesis,structure, and catalytic activity |
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| Authors: | A V Mekhaev A V Pestov P A Slepukhin Yu G Yatluk M G Pervova M A Samorukova O N Chupakhin |
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| Institution: | (1) School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, People’s Republic of China; |
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| Abstract: | Palladium(II) complex with 6-(2-hydroxy-5-methylphenyl)-3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one was synthesized for the first time. The ligand was prepared from 3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one and 4-methylphenol via nucleophilic substitution of hydrogen (SNH reaction). The complex was readily soluble in basic medium, and it effectively catalyzed Mizoroki-Heck reaction. |
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