| 基于环糊精的原子转移自由基聚合 |
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| 引用本文： | 张华承,刘召娜,辛飞飞,李月明,孔丽,郝爱友.基于环糊精的原子转移自由基聚合[J].有机化学,2011,31(11). |
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| 作者姓名： | 张华承 刘召娜 辛飞飞 李月明 孔丽 郝爱友 |
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| 作者单位： | 山东大学化学与化工学院 济南250100 |
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| 摘 要： | 综述了近年来基于环糊精的原子转移自由基聚合的最新进展.其中,基于环糊精合成化学的原子转移自由基聚合主要表现在:一方面,通过原子转移自由基聚合反应实现环糊精母体的共价键修饰；另一方面,利用该反应参与构筑非共价键的环糊精自组装体系.而通过原子转移自由基聚合反应获得的这些新型环糊精衍生物和自组装体系还可以被进一步应用到有机合成化学、复杂“智能型”超分子自组装体系的构筑、药物输运与控缓释工具、蛋白识别以及手性分离等领域.
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| 关 键 词： | 环糊精 原子转移自由基聚合 超分子化学 合成 应用 |
Atom Transfer Radical Polymerization Based on Cyclodextrin |
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| Zhang, Huacheng,Liu, Zhaona,Xin, Feifei,Li, Yueming,Kong, Li,Hao, Aiyou.Atom Transfer Radical Polymerization Based on Cyclodextrin[J].Chinese Journal of Organic Chemistry,2011,31(11). |
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| Authors: | Zhang Huacheng Liu Zhaona Xin Feifei Li Yueming Kong Li Hao Aiyou |
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| Institution: | Zhang,Huacheng Liu,Zhaona Xin,Feifei Li,Yueming Kong,Li Hao,Aiyou (School of Chemistry and Chemical Engineering,Shandong University,Jinan 250100) |
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| Abstract: | The recent progress in atom transfer radical polymerization(ATRP) based on cyclodextrin has been reviewed.In cyclodextrin synthesis chemistry,ATRP can be applied to covalently modifying the native cyclodextrins and can participate in constructing cyclodextrins assemblies by noncovalent interactions.And these novel cyclodextrins and assemblies obtained by ATRP can be further applied to the fields such as or-ganic synthesis,complicated smart supramolecular assemblies,drug delivery and release system,protein r... |
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| Keywords: | cyclodextrin atom transfer radical polymerization supramolecular chemistry synthesis ap-plication |
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