| Synthesis and Crystal Structure of [{Cd(hmbdc)(H_2O)_3}·2H_2O]_n |
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| 引用本文： | 胡月华,王燕,王作为,李一志,郑和根.Synthesis and Crystal Structure of [{Cd(hmbdc)(H_2O)_3}·2H_2O]_n[J].结构化学,2007,26(4):423-426. |
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| 作者姓名： | 胡月华 王燕 王作为 李一志 郑和根 |
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| 作者单位： | Huangshan University，Coordination Chemistry Institute State Key Laboratory of Coordination Chemistry College of Chemistry and Chemical Engineering Nanjing University，Coordination Chemistry Institute State Key Laboratory of Coordination Chemistry College of Chemistry and Chemical Engineering Nanjing University，Coordination Chemistry Institute State Key Laboratory of Coordination Chemistry College of Chemistry and Chemical Engineering Nanjing University，Coordination Chemistry Institute State Key Laboratory of Coordination Chemistry College of Chemistry and Chemical Engineering Nanjing University，Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China，Huangshan 245041 China，Nanjing 210093 China，Nanjing 210093 China，Nanjing 210093 China，Nanjing 210093 China |
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| 基金项目： | Supported by the National Natural Science Foundation of China (20571039, 20171020)，the Ministry of Education of China (20050284031) |
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| 摘 要： | A novel coordination polymer {Cd(hmbdc)(H2O)3}·2H2O]n (hmbdc = 5-hydroxy- isophthalic acid) has been synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P21/c, with a = 9.599(3), b = 18.699(5), c = 7.557(2) , β = 108.198(4)°, V = 1288.6(6) 3, Z = 4, Mr = 382.60, Dc = 1.972 g/cm3, F(000) = 760, μ = 1.740, the final R = 0.0555 and wR = 0.0995 for 1732 observed reflections with I > 2σ(I). The structural analysis shows that the intermolecular hydrogen bonds and π-π interactions result in a three-dimensional supramolecular framework.
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| 关 键 词： | Cd(Ⅱ) complex crystal structure hydrogen bond network structure |
Synthesis and Crystal Structure of [{Cd(hmbdc)(H_2O)_3}·2H_2O]_n |
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| HU Yue-Hua,WANG Yan,WANG Zuo-Wei,LI Yi-Zhi,ZHENG He-Gen,.Synthesis and Crystal Structure of [{Cd(hmbdc)(H_2O)_3}·2H_2O]_n[J].Chinese Journal of Structural Chemistry,2007,26(4):423-426. |
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| Authors: | HU Yue-Hua WANG Yan WANG Zuo-Wei LI Yi-Zhi ZHENG He-Gen |
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| Abstract: | A novel coordination polymer {Cd(hmbdc)(H2O)3}·2H2O]n (hmbdc = 5-hydroxy- isophthalic acid) has been synthesized and characterized by elemental analysis, IR spectra and single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P21/c, with a = 9.599(3), b = 18.699(5), c = 7.557(2) , β = 108.198(4)°, V = 1288.6(6) 3, Z = 4, Mr = 382.60, Dc = 1.972 g/cm3, F(000) = 760, μ = 1.740, the final R = 0.0555 and wR = 0.0995 for 1732 observed reflections with I > 2σ(I). The structural analysis shows that the intermolecular hydrogen bonds and π-π interactions result in a three-dimensional supramolecular framework. |
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| Keywords: | Cd(II) complex crystal structure hydrogen bond network structure |
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